copies should be ordered. Buy the Full Version. The initial rate of decomposition of the n-butane was.50-order with respect to the partial pressure of the n-butane. The surfaces of the gold reactor had been acid-treated to remove oxide impurities. Abstract, experimental Joule-Thomson measurements were made on gaseous propane at temperatures from 100 to 280F and at pressures from 8 to 66 psia. Research Advisor(s Corcoran, William Harrison, thesis Committee: Unknown, Unknown, defense Date:, record Number: Caltechthesis. Some preliminary experiments were performed in the partial oxidation of n-butane. Thesis Committee: Unknown, Unknown, defense Date:, funders: Funding Agency, grant Number.
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Joule-Thomson measurements were also made on gaseous n-butane at temperatures from 100 to 280 and at pressures from 8 to 42 psia.
For propane, the values of these measurements ranged from.07986F/psi at 280F and.01 psia.19685F/psi at 100F and.15 psia.
A study of the pyrolysis of n- butane was carried out using an all-gold tubular reactor.
ID Code: 9370, collection: Caltechthesis, deposited By: Leslie Granillo, deposited On: 23:18, last Modified: 23:18. Division: Chemistry and Chemical Engineering, major Option: Chemical Engineering, thesis Availability: Public (worldwide access). Calculated values of the Joule-Thomson coefficient from other types of p-v-t data did agree with the present measurements for n-butane. Photographic materials on pages 79-81 are essential and will not reproduced clearly on Xerox copies. A free radical mechanism, similar to that originally proposed by Rice, accounted satisfactorily for the distribution of products. For propane, the values of these measurements ranged from.07986F/psi at 280F and.01 psia.19685F/psi at 100F and.15 psia. The flow rate was shown to have an appreciable effect on non-isenthalpic Joule-Thomson measurements. For n-butane, the measurements of this study did not agree with previous Joule-Thomson measurements made in the Laboratory in 1935. The experimental values have a maximum error.5 percent. ID Code: 9117, collection: Caltechthesis, deposited By: Leslie Granillo, deposited On: 21:03.